先得的14.51克白色沉淀是BaSO4和BaCO3的混合沉淀
加稀硝酸时BaCO3溶解,剩余4.66克沉淀是BaSO4,
溶解的BaCO3质量=14.51-4.66=9.85g
n(Na2CO3)=n(BaCO3)=9.85/197=0.05mol
c(Na2CO3)=0.05/0.05=1mol/L
n(Na2SO4)=n(BaSO4)=4.66/233=0.02mol
c(Na2SO4)=0.02/0.05=0.4mol/L
n(CO2)=n(BaCO3)=0.05mol
V(CO2)=22.4*0.05=1.12L